A facile and greener synthesis of butylene carbonate via CO2 utilisation using a novel copper–zirconia oxide/graphene catalyst

Conference paper


Onyenkeadi, V, Aboelazayem, O and Saha, B (2018). A facile and greener synthesis of butylene carbonate via CO2 utilisation using a novel copper–zirconia oxide/graphene catalyst. The 16th International Conference on Carbon Dioxide Utilization (ICCDU XVI). Rio De Janeiro, Brazil 27 - 30 Aug 2018
AuthorsOnyenkeadi, V, Aboelazayem, O and Saha, B
TypeConference paper
Abstract

The cumulative CO2 emissions in the atmosphere are causing serious changes in climate via global warming because of continuous burning of fossil fuel. However, the scientific community has identified the means to alleviate the environmental burden through carbon capture and storage, and utilisation of CO2 for synthesis of value added chemicals. The latter greener approach for utilising CO2 as a C1 feedstock for organic chemical synthesis is extremely beneficial not only for the chemical industry but also for contributing to limit its emissions. The direct synthesis of butylene carbonate (BC) through cycloaddition reaction of CO2 to butylene oxide (BO) is of a great commercial interest. BC is an excellent reactive intermediate material used in industry for the production of surfactant, plasticisers, polymers and can also be used as a solvent for wood binder resins, degreasing, paint remover, lubricants and the foundry, sand binders as well as lithium battery because of its high polarity property. Several reaction routes have been attempted for BC production, e.g. phosgene, oxidative carboxylation, direct synthesis using homogeneous catalyst and direct synthesis using a heterogeneous catalyst. The latter being the most attractive route due to the inexpensive raw material, ease of catalyst recovery and avoidance of corrosive reagents, such as phosgene. In the present work, a facile and environmentally benign method has been developed for the synthesis of highly efficient graphene-inorganic heterogeneous catalyst, represented as Cu–Zr/GO inorganic composite. The graphene-inorganic heterogeneous catalyst has been characterised using transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), X-ray powder diffraction (XRD) and nitrogen adsorption/desorption method (for measuring BET surface area and pore size distribution). Copper-zirconia/graphene inorganic composite catalyst (Cu–Zr–GO) as heat treated at 723 K exhibited high catalytic activity as compared to other reported heterogeneous catalysts in the absence of any organic solvent with 71% yield of BC, and 87% selectivity towards BO at the reaction conditions of 423 K, 80 bar in 12 h. The use of Box-Behnken Design (BBD) from Response Surface Methodology (RSM) has been employed to investigate the single and interactive effect of several independent reaction variables that include temperature, pressure, catalyst loading, heat treatment and time, on the conversion of BO and yield of BC. Two quadratic regression models have been developed representing an empirical relationship between each reaction response and all the independent variables. The predicted models have been validated statistically and experimentally, where very high agreement has been observed between predicted and experimental results with approximate relative errors of ±1.25% for BO conversion and ± 0.75% for BC yield. Acknowledgments We acknowledge the financial support from London South Bank University and The British University in Egypt.

KeywordsCO2 utilisation; butylene oxide; butylene carbonate; , graphene-inorganic heterogeneous catalyst; characterisation
Year2018
Accepted author manuscript
License
File Access Level
Open
Publication dates
Print27 Aug 2018
Publication process dates
Deposited14 Sep 2018
Accepted06 Jul 2018
Permalink -

https://openresearch.lsbu.ac.uk/item/869q0

Download files


Accepted author manuscript
ICCDU_Abstract_Onyenkeadi_Aboelazayem_Saha_LSBU.doc
License: CC BY 4.0
File access level: Open

  • 196
    total views
  • 42
    total downloads
  • 2
    views this month
  • 0
    downloads this month

Export as

Related outputs

Comparative Production of Bio-Oil from In Situ Catalytic Upgrading of Fast Pyrolysis of Lignocellulosic Biomass
Abdulkhani, A., Zadeh, Z.E., Bawa, S.G., Sun, F., Madadi, M., Zhang, X. and Saha, B. (2023). Comparative Production of Bio-Oil from In Situ Catalytic Upgrading of Fast Pyrolysis of Lignocellulosic Biomass. Energies. 16 (6), p. 2715. https://doi.org/10.3390/en16062715
Synthesis of green thermo-responsive amphoteric terpolymer functionalized silica nanocomposite derived from waste vegetable oil triglycerides for enhanced oil recovery (EOR)
Mahran, S., Attia A. and Saha, B. (2022). Synthesis of green thermo-responsive amphoteric terpolymer functionalized silica nanocomposite derived from waste vegetable oil triglycerides for enhanced oil recovery (EOR). Journal of Cleaner Production. 380 (Part 2), p. 135024. https://doi.org/10.1016/j.jclepro.2022.135024
A renewable lignin-derived bio-oil for boosting the oxidation stability of biodiesel
Umar, Y., Velasco, O., Abdelaziz, O., Aboelazayem, O., Gadalla, M., Hulteberg, C.P. and Saha, B. (2021). A renewable lignin-derived bio-oil for boosting the oxidation stability of biodiesel. Renewable Energy. 182, pp. 867-878. https://doi.org/10.1016/j.renene.2021.10.061
A comparative production and characterisation of fast pyrolysis bio-oil from Populus and Spruce woods
Echresh Zadeh, Z., Abdulkhani, A. and Saha, B. (2020). A comparative production and characterisation of fast pyrolysis bio-oil from Populus and Spruce woods. Energy. https://doi.org/10.1016/j.energy.2020.118930
Porous boron nitride: an effective adsorbent for carbon dioxide capture
Hojatisaeidi, F., Mureddu, M., Dessi, F., Pettinau, A., Durand, G. and Saha, B. (2020). Porous boron nitride: an effective adsorbent for carbon dioxide capture. Environmental Chemistry Group Bulletin.
Advanced process integration for supercritical production of biodiesel: Residual waste heat recovery via organic Rankine cycle (ORC)
Aboelazayem, O, Gadalla, M, Alhajri, I and Saha, B (2020). Advanced process integration for supercritical production of biodiesel: Residual waste heat recovery via organic Rankine cycle (ORC). Renewable Energy. 164, pp. 433-443. https://doi.org/10.1016/j.renene.2020.09.058
Recent Insights into Lignocellulosic Biomass Pyrolysis: A Critical Review on Pretreatment, Characterization, and Products Upgrading
Zadeh, ZE, Abdulkhani, A, Aboelazayem, O and Saha, B (2020). Recent Insights into Lignocellulosic Biomass Pyrolysis: A Critical Review on Pretreatment, Characterization, and Products Upgrading. Processes. 8 (7), pp. 799-799. https://doi.org/10.3390/pr8070799
Metal-Free Modified Boron Nitride for Enhanced CO2 Capture
Hojatisaeidi, F., Mureddu, M., Dessì, F., Durand, G. and Saha, B. (2020). Metal-Free Modified Boron Nitride for Enhanced CO2 Capture. Energies. 13 (3), pp. 549-549. https://doi.org/10.3390/en13030549
Characterization of fast pyrolysis bio-oil from hardwood and softwood lignin
Zadeh, ZE, Abdulkhani, A and Saha, B (2020). Characterization of fast pyrolysis bio-oil from hardwood and softwood lignin. Energies. 13 (4), pp. 887-887. https://doi.org/10.3390/en13040887
Comparison of catalytic activity of ZIF-8 and Zr/ZIF-8 for greener synthesis of chloromethyl ethylene carbonate by CO2 utilization
Olaniyan, B and Saha, B (2020). Comparison of catalytic activity of ZIF-8 and Zr/ZIF-8 for greener synthesis of chloromethyl ethylene carbonate by CO2 utilization. Energies. 13 (3), pp. 521-521. https://doi.org/10.3390/en13030521
Multiobjective optimization for the greener synthesis of chloromethyl ethylene carbonate by CO2 and epichlorohydrin via response surface methodology
Olaniyan, B and Saha, B (2020). Multiobjective optimization for the greener synthesis of chloromethyl ethylene carbonate by CO2 and epichlorohydrin via response surface methodology. Energies. 13 (3), pp. 741-741. https://doi.org/10.3390/en13030741
Development of an environmentally benign and optimised biodiesel production process
Aboelazayem, O (2019). Development of an environmentally benign and optimised biodiesel production process. PhD Thesis London South Bank University School of Engineering https://doi.org/10.18744/LSBU.003293
Bio fuel: Environmentally benign biodiesel production from renewable sources
Abidin, SZ and Saha, B (2017). Bio fuel: Environmentally benign biodiesel production from renewable sources. in: The Water-Food-Energy Nexus: Processes, Technologies, and Challenges CRC Press. pp. 333-364
A permeable particle container
Saha, B, Ambroziak, K, Sherrington, DC and Mbeleck, R (2016). A permeable particle container.
Design of an integrated process for biodiesel production using supercritical methanolysis: Simultaneous work and energy integration
Aboelazayem, O., Gadalla, M., Alhajri, I. and Saha, B. (2019). Design of an integrated process for biodiesel production using supercritical methanolysis: Simultaneous work and energy integration. 12th International Conference on Sustainable Energy & Environmental Protection (SEEP 2019). Sharjah, UAE 18 - 21 Nov 2019
Valorisation of high acid value waste cooking oil into biodiesel via supercritical methanolysis
Umar, Y., Aboelazayem, O., Gadalla, M. and Saha, B. (2019). Valorisation of high acid value waste cooking oil into biodiesel via supercritical methanolysis. ChemEngDayUK 2019. Edinburgh, Scotland 08 - 09 Apr 2019
Supercritical methanolysis of waste cooking oil for biodiesel synthesis: Experimental and simulation assessments
Aboelazayem, O., Zadah, Z., Gadalla, M. and Saha, B. (2019). Supercritical methanolysis of waste cooking oil for biodiesel synthesis: Experimental and simulation assessments. ECOS2019 – 32nd International Conference on Efficiency, Cost, Optimisation, Simulation and Environmental Impact on Energy Systems. Wroclaw, Poland 23 - 28 Jun 2019
A comparative structural characterisation of different lignin biomass
Echresh, Z., Abdulkhani, A., Gadalla, M. and Saha, B. (2019). A comparative structural characterisation of different lignin biomass. ECOS2019 – 32nd International Conference on Efficiency, Cost, Optimisation, Simulation and Environmental Impact on Energy Systems. Wroclaw, Poland 23 - 28 Jun 2019
Synthesis and characterization of a novel amphoteric terpolymer nanocomposite for enhanced oil recovery applications
Mahran, S., Attia, A., Zadeh, Z. and Saha, B. (2019). Synthesis and characterization of a novel amphoteric terpolymer nanocomposite for enhanced oil recovery applications. ECOS2019 – 32nd International Conference on Efficiency, Cost, Optimisation, Simulation and Environmental Impact on Energy Systems. Wroclaw, Poland 23 - 28 Jun 2019
Direct synthesis of chloromethyl ethylene carbonate via CO2 utilisation using a novel Zr/ZIF-8 catalyst
Olaniyan, B. and Saha, B. (2019). Direct synthesis of chloromethyl ethylene carbonate via CO2 utilisation using a novel Zr/ZIF-8 catalyst. The 17th International Conference on Carbon Dioxide Utilization (ICCDU 2019). Aachen, Ggermany 23 - 27 Jun 2019
Systematic multivariate optimisation of butylene carbonate synthesis via CO <inf>2</inf> utilisation using graphene-inorganic nanocomposite catalysts
Onyenkeadi, V, Aboelazayem, O and Saha, B (2019). Systematic multivariate optimisation of butylene carbonate synthesis via CO <inf>2</inf> utilisation using graphene-inorganic nanocomposite catalysts. Catalysis Today. https://doi.org/10.1016/j.cattod.2019.03.027
Next frontiers in cleaner synthesis: 3D printed graphene-supported CeZrLa mixed-oxide nanocatalyst for CO2 utilisation and direct propylene carbonate production
Middelkoop, V, Slater, T, Florea, M, Neațu, F, Danaci, S, Onyenkeadi, V, Boonen, K, Saha, B., Baragau, I. and Kellici, S (2019). Next frontiers in cleaner synthesis: 3D printed graphene-supported CeZrLa mixed-oxide nanocatalyst for CO2 utilisation and direct propylene carbonate production. Journal of Cleaner Production. 214, pp. 606-614. https://doi.org/10.1016/j.jclepro.2018.12.274
Derivatisation-free characterisation and supercritical conversion of free fatty acids into biodiesel from high acid value waste cooking oil
Aboelazayem, O, Gadalla, M and Saha, B (2019). Derivatisation-free characterisation and supercritical conversion of free fatty acids into biodiesel from high acid value waste cooking oil. Renewable Energy. 143, pp. 77-90. https://doi.org/10.1016/j.renene.2019.04.106
Waste cooking oil valorisation into biodiesel using supercritical methanolysis: critical assessment on the effect of water content
Umar, Y, Aboelazayem, O, Echresh, Z, Gadalla, M and Saha, B (2019). Waste cooking oil valorisation into biodiesel using supercritical methanolysis: critical assessment on the effect of water content. EUBCE 2019 – 27th European Biomass Conference and Exhibition. Lisbon, Portugal 26 - 31 May 2019
Analytical pyrolysis study of different lignin biomass
Echresh, Z, Abdulkhani, A and Saha, B (2019). Analytical pyrolysis study of different lignin biomass. EUBCE 2019 – 27th European Biomass Conference and Exhibition. Lisbon, Portugal 26 - 31 May 2019
A continuous process for the liquid phase epoxidation of an olefinic compound
Saha, B, Ambroziak, K, Sherrington, DC and Mbeleck, R (2018). A continuous process for the liquid phase epoxidation of an olefinic compound.
Systematic multivariate optimization of biodiesel synthesis from high acid value waste cooking oil: A response surface methodology approach
Aboelazayem, O., Gadalla, M. and Saha, B. (2018). Systematic multivariate optimization of biodiesel synthesis from high acid value waste cooking oil: A response surface methodology approach. 7th International Symposium on Energy from Biomass and Waste. Venice, Italy 15 - 18 Oct 2019
Greener synthesis of dimethyl carbonate using a novel tin-zirconia/graphene nanocomposite catalyst
Saada, R, Aboelazayem, O, Kellici, S, Heil, T, Morgan, D, Lampronti, G and Saha, B (2018). Greener synthesis of dimethyl carbonate using a novel tin-zirconia/graphene nanocomposite catalyst. Applied Catalysis B: Environmental. 226, pp. 451-462. https://doi.org/10.1016/j.apcatb.2017.12.081
Supercritical methanolysis of waste cooking oil for biodiesel production: Experimental assessment for evaluating the effect of free fatty acids content
Aboelazayem, O, Gadalla, M and Saha, B (2018). Supercritical methanolysis of waste cooking oil for biodiesel production: Experimental assessment for evaluating the effect of free fatty acids content. EUBCE 2018 – 26th European Biomass Conference and Exhibition Proceedings. Copenhagen, Denmark 14 - 17 May 2018
A review on polymer flooding in enhanced oil recovery under harsh conditions
Mahran, S, Attia, A and Saha, B (2018). A review on polymer flooding in enhanced oil recovery under harsh conditions. 11th International Sustainable Energy & Environmental Protection Conference. Paisley, Scotland 08 - 11 May 2018
Non-catalytic production of biodiesel using supercritical methanol: a brief review
Aboelazayem, O, Gadalla, M and Saha, B (2018). Non-catalytic production of biodiesel using supercritical methanol: a brief review. 11th International Sustainable Energy & Environmental Protection Conference. Paisley, Scotland 08 - 11 May 2018
Greener synthesis of butylene carbonate via CO2 utilisation using graphene-inorganic nanocomposite catalysts
Onyenkeadi, V, Aboelazayem, O, Kellici, S and Saha, B (2018). Greener synthesis of butylene carbonate via CO2 utilisation using graphene-inorganic nanocomposite catalysts. GPE 2018 – 6th International Congress on Green Process Engineering. Toulouse, France 03 - 06 Jun 2018
Design and simulation of an integrated process for biodiesel production from waste cooking oil using supercritical methanolysis
Aboelazayem, O, Gadalla, M and Saha, B (2018). Design and simulation of an integrated process for biodiesel production from waste cooking oil using supercritical methanolysis. Energy. 161, pp. 299-307. https://doi.org/10.1016/j.energy.2018.07.139
Valorisation of high acid value waste cooking oil into biodiesel using supercritical methanolysis: Experimental assessment and statistical optimisation on typical Egyptian feedstock
Aboelazayem, O, Gadalla, M and Saha, B (2018). Valorisation of high acid value waste cooking oil into biodiesel using supercritical methanolysis: Experimental assessment and statistical optimisation on typical Egyptian feedstock. Energy. 162, pp. 408-420. https://doi.org/10.1016/j.energy.2018.07.194
Greener synthesis of 1,2-butylene carbonate from CO2 using graphene-inorganic nanocomposite catalyst
Onyenkeadi, V, Kellici, S and Saha, B (2018). Greener synthesis of 1,2-butylene carbonate from CO2 using graphene-inorganic nanocomposite catalyst. Energy. 165, pp. 867-876. https://doi.org/10.1016/j.energy.2018.09.135
Environmentally benign biodiesel production from renewable sources
Zainal Abidin, S and Saha, B (2017). Environmentally benign biodiesel production from renewable sources. in: Mujtaba, IM, Srinivasan, R and Elbashir, NO (ed.) The Water-Food-Energy Nexus Processes, Technologies, and Challenges Boca Raton, Florida, USA CRC Press.
Optimising biodiesel production from waste cooking oil using supercritical methanol
Aboelazayem, O, Gadalla, M and Saha, B (2017). Optimising biodiesel production from waste cooking oil using supercritical methanol. London South Bank University.
Greener and sustainable approach for the synthesis of commercially important epoxide building blocks using polymer-supported Mo(VI) complexes as catalysts
Mohammed, ML and Saha, B (2016). Greener and sustainable approach for the synthesis of commercially important epoxide building blocks using polymer-supported Mo(VI) complexes as catalysts. in: SenGupta, AK (ed.) Ion Exchange and Solvent Extraction CRC Press.
Green Process Engineering as the Key to Future Processes
Patel, D, Kellici, S and Saha, B (2014). Green Process Engineering as the Key to Future Processes. Processes. 2 (1), pp. 311-332.
Efficient and selective polymer supported Mo(VI) catalyst for alkene epoxidation in batch and continuous reactors
Saha, B, Mohammed, ML and Mbeleck, R (2015). Efficient and selective polymer supported Mo(VI) catalyst for alkene epoxidation in batch and continuous reactors. Polymer Chemistry. https://doi.org/10.1039/C5PY01147G
Rapid synthesis of graphene quantum dots using a continuous hydrothermal flow synthesis approach
Kellici, S, Acord, J, Power, N, Morgan, D, Coppo, P, Heil, T and Saha, B (2017). Rapid synthesis of graphene quantum dots using a continuous hydrothermal flow synthesis approach. RSC Advances. 24, pp. 14716-14720. https://doi.org/10.1039/c7ra00127d
Carbon dioxide utilization by graphene based nanocomposite materials as catalysts
Saha, B (2017). Carbon dioxide utilization by graphene based nanocomposite materials as catalysts. International Conference on Nanotechnology Applications: Chemical, Energy and Environment (NACEE-2017). Surat, India 22 - 23 Mar 2017
Greener synthesis of styrene carbonate from CO2 using heterogeneous catalyst
Onyenkeadi, V and Saha, B (2017). Greener synthesis of styrene carbonate from CO2 using heterogeneous catalyst. ChemEngDayUK2017 Better Life, Better World. Birmingham 27 - 28 Mar 2017
Biodiesel production from high acid value waste cooking oil using supercritical methanol: Esterification kinetics of free fatty acids
Aboelazayem, O, Abdelaziz, O, Gadalla, M, Hulteberg, C and Saha, B (2017). Biodiesel production from high acid value waste cooking oil using supercritical methanol: Esterification kinetics of free fatty acids. EUBCE 2017 – Proceedings of the 25th European Biomass Conference and Exhibition. Stockholm, Sweden 12 - 15 Jun 2017
Biodiesel production from waste cooking oil via supercritical methanol: Optimisation and reactor simulation
Saha, B, Aboelazayem, O and Gadalla, M (2017). Biodiesel production from waste cooking oil via supercritical methanol: Optimisation and reactor simulation. Renewable Energy. 124, pp. 144-154. https://doi.org/10.1016/j.renene.2017.06.076
Greener synthesis of 1, 2 butylene carbonate from CO2 using graphene-inorganic nanocomposite catalysis
Onyenkeadi, V, Kellici, S and Saha, B (2017). Greener synthesis of 1, 2 butylene carbonate from CO2 using graphene-inorganic nanocomposite catalysis. SEEP 2017 –10th International Conference on Sustainable Energy & Environmental Protection. Bled, Slovenia 27 - 30 Jun 2017
Optimising biodiesel production from high acid value waste cooking oil using supercritical methanol
Aboelazayem, O, Gadalla, M and Saha, B (2017). Optimising biodiesel production from high acid value waste cooking oil using supercritical methanol. SEEP 2017 – Proceedings of the 10th International Conference on Sustainable Energy & Environmental Protection. Bled, Slovenia 27 - 30 Jun 2017
A comparative study on biodiesel production from waste cooking oils obtained from different sources using supercritical methanol
Aboelazayem, O, Gadalla, M and Saha, B (2017). A comparative study on biodiesel production from waste cooking oils obtained from different sources using supercritical methanol. Journal of Bioremediation & Biodegradation. 8 (5), pp. 56-56. https://doi.org/10.4172/2155-6199-C1-008
Greener synthesis of styrene carbonate from CO2 using graphene-inorganic nanocomposite catalysts
Onyenkeadi, V, Kellici, S and Saha, B (2017). Greener synthesis of styrene carbonate from CO2 using graphene-inorganic nanocomposite catalysts. 10th World Congress of Chemical Engineering (WCCE10). Barcelona, Spain 01 - 05 Oct 2017
One-step production of biodiesel from high acid value waste cooking oil using supercritical methanol
Aboelazayem, O, Gadalla, M and Saha, B (2017). One-step production of biodiesel from high acid value waste cooking oil using supercritical methanol. 10th World Congress of Chemical Engineering (WCCE10). Barcelona, Spain 01 - 05 Oct 2017
An experimental-based energy integrated process for biodiesel production from waste cooking oil using supercritical methanol
Aboelazayem, O, Gadalla, M and Saha, B (2017). An experimental-based energy integrated process for biodiesel production from waste cooking oil using supercritical methanol. Chemical Engineering Transactions. 61. https://doi.org/10.3303/CET1761272
Catalysis in multifunctional reactors
Mahajani, S and Saha, B (2016). Catalysis in multifunctional reactors. Physical Sciences Reviews. 1 (2). https://doi.org/10.1515/psr-2015-0014
A continuous-flow apprach to alkene epoxidation catalysed by Polystyrene 2-(Aminomethyl)Pyridine supported Mo(VI) complex
Saha, B, Mohammed, ML and Mbeleck, R (2016). A continuous-flow apprach to alkene epoxidation catalysed by Polystyrene 2-(Aminomethyl)Pyridine supported Mo(VI) complex. 5th International Conference on Green Process Engineering (GPE 2016),. Quebec, Canada 19 - 24 Jun 2016
Greener and Sustainable Alkene Epoxidation Process
Saha, B, Mohammed, ML and Mbeleck, R (2016). Greener and Sustainable Alkene Epoxidation Process. 1st BUE Annual Conference & Exhibition-BUE ACE1. Cairo, Egypt 08 - 10 Nov 2016
Optimisation of biodiesel production from waste cooking oil under supercritical conditions
Aboelazayem, O, Gadalla, M and Saha, B (2016). Optimisation of biodiesel production from waste cooking oil under supercritical conditions. Venice 2016 – Proceedings of the 6th International Symposium on Energy from Biomass and Waste. Venice, Italy 14 - 16 Nov 2016
Efficient and selective molybdenum based heterogeneous catalyst for alkene epoxidation using batch and continuous reactors
Mohammed, M., Mbeleck, R and Saha, B (2015). Efficient and selective molybdenum based heterogeneous catalyst for alkene epoxidation using batch and continuous reactors. Polymer Chemistry. 6, pp. 7308-7319. https://doi.org/10.1039/C5PY01147G